1803562-29-9 | methyl 2,2,2-trifluoroethyl oxalate

CAS:1803562-29-9 | methyl 2,2,2-trifluoroethyl oxalate,Description

“Methyl 2,2,2-trifluoroethyl oxalate” is a chemical compound with the CAS Number: 1803562-29-9. It has a molecular weight of 186.09and its IUPAC name is methyl (2,2,2-trifluoroethyl) oxalate.

Synthesis Analysis

A simple parallel synthesis approach to unsymmetrical N1,N2-substituted aliphatic oxamides using methyl (2,2,2-trifluoroethyl) oxalate and bis(2,2,2-trifluoroethyl) oxalate was developed. The method was validated on a 52-membered set of the oxamides, derived mainly from hindered primary and secondary aliphatic amines.

Molecular Structure Analysis

The InChI code for “Methyl 2,2,2-trifluoroethyl oxalate” is 1S/C5H5F3O4/c1-11-3(9)4(10)12-2-5(6,7)8/h2H2,1H3. The InChI key is QSNCGGSHECUXPJ-UHFFFAOYSA-N.

Physical And Chemical Properties Analysis

“Methyl 2,2,2-trifluoroethyl oxalate” is a liquid at room temperature. It should be stored at a temperature of 4 degrees Celsius.

Scientific Research Applications

Synthesis of Aliphatic Oxamides

Methyl 2,2,2-trifluoroethyl oxalate has been employed in the parallel synthesis of hindered aliphatic oxamides. This method, involving both methyl (2,2,2-trifluoroethyl) oxalate and bis(2,2,2-trifluoroethyl) oxalate, has been validated on a diverse set of oxamides derived from primary and secondary aliphatic amines, showcasing moderate yields and high overall success rates (Bogolubsky et al., 2016) .

Electrochemical Capacitor Electrolytes

In the domain of electrochemical capacitors, certain fluorinated additives including methyl (2,2,2-trifluoroethyl) oxalate have been investigated to enhance stability at higher voltages. This research is pivotal in advancing the operating limits of supercapacitors, thereby improving their compatibility with lithium-ion battery cells for hybrid configurations (Krause et al., 2021).

Lithium-Ion Battery Electrolytes

The compound plays a role in developing safer electrolytes for lithium-ion batteries. In a mixture with propylene carbonate and tris(2,2,2-trifluoroethyl)phosphate, it contributes to non-flammable characteristics and enhances compatibility with graphite anodes, showing potential for practical applications in battery technology (Gu et al., 2020).

Solid Electrolyte Interphase Film Analysis

Methyl 2,2,2-trifluoroethyl oxalate is significant in the analysis of solid electrolyte interphase (SEI) films in lithium-ion batteries. Studies have utilized this compound in electrolytes to understand the nature and composition of SEI films, which is crucial for improving battery performance and durability (Li et al., 2012).

Photoreduction Studies

This compound has been used in photoreduction studies, specifically in the investigation of the photolysis of crystal violet oxalate in various solutions and films. Such research enhances our understanding of photoreduction mechanisms and has applications in photochemistry (Leaver, 1972).

Chemiluminescent Analysis

Methyl 2,2,2-trifluoroethyl oxalate is instrumental in chemiluminescent analysis, such as in the development of a regenerable chemiluminescent polymer for chemical analysis. This innovative approach offers environmental and cost benefits by reusing the active compound (Lowry et al., 2004).

Green Chemistry Applications

In green chemistry, a new oxalate ester derived from methyl salicylate has been synthesized as a replacement for typical halogenated oxalate esters used in chemiluminescence demonstrations, demonstrating the compound's versatility and environmentally friendly applications (Cambrea et al., 2013).

Safety And Hazards

The safety information pictograms for “Methyl 2,2,2-trifluoroethyl oxalate” are GHS02 and GHS07. The signal word is "Warning". For more detailed safety and hazard information, please refer to the Material Safety Data Sheet (MSDS).

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