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1-(Trifluoromethylthio)pyrrolidine-2,5-dione, otherwise known as TFMPP, is a synthetic pyrrolidine derivative that has been studied extensively due to its potential applications in scientific research. It is a colorless solid that is soluble in water and organic solvents, and has a melting point of 109-110°C. TFMPP is ...
1-(Trifluoromethylthio)pyrrolidine-2,5-dione, otherwise known as TFMPP, is a synthetic pyrrolidine derivative that has been studied extensively due to its potential applications in scientific research. It is a colorless solid that is soluble in water and organic solvents, and has a melting point of 109-110°C. TFMPP is of particular interest due to its unique properties, which make it a useful compound for a variety of research applications.
1-(Trifluoromethylthio)pyrrolidine-2,5-dione has been identified as a class of organic Mannich base system with effective performance in antioxidant activity. Vibrational analysis, using experimental FT-IR and FT-Raman spectra, has been carried out, providing insights into structure-property relationships and bonding behaviors, as well as the nature of hybridization in such compounds (Boobalan et al., 2014).
This compound plays a key role in the photocatalytic trifluoromethylthiolation process of aromatic alkenes. A specific photoredox system involving 1-(trifluoromethylthio)pyrrolidine-2,5-dione facilitates the efficient generation of a trifluoromethansulfenyl radical, leading to the regioselective installation of a CF3S group onto vicinal carbon atoms through redox-neutral processes (Li, Koike & Akita, 2017).
New derivatives of pyrrolidine-2,5-dione, such as 1-phenyl-1H-pyrrole-2,5-dione (PPD) and 1-(4-methylphenyl)-1H-pyrrole-2,5-dione (MPPD), have shown significant inhibitory action against corrosion of carbon steel in acidic media. These compounds exhibit increased inhibition efficiency with concentration, acting as mixed-type inhibitors (Zarrouk et al., 2015).
The synthesis of 4-substituted 1-(4-iodophenyl)pyrrolidine-2,5-dione derivatives through addition reactions with amines and thiols has been documented. These derivatives can undergo further functionalization through oxidation, alkylation, and allylation reactions, offering moderate-to-good yields (Ali et al., 2015).
Research has shown that pyrrolidine-2,5-dione and maleimide, vital organic scaffolds, can be interconverted. The study of tosylation of trans-3,4-dihydroxypyrrolidine-2,5-dione has provided insights into thermodynamic and kinetic factors affecting the reaction, as well as the understanding of pyrrolidine-2,5-diones and maleimides properties (Yan et al., 2018).
Product Name : | 1-(Trifluoromethylthio)pyrrolidine-2,5-dione | ||
CAS No. : | 183267-04-1 | Molecular Weight : | 199.15 |
MDL No. : | MFCD30187362 | Purity/ Specification : | |
Molecular Formula : | C5H4F3NO2S | Storage : | Keep in dark place,Inert atmosphere,2-8°C |
Boiling Point : | - |
GHS Pictogram : | |||
Signal Word : | Danger | Precautionary Statements : | P501-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P337+P313-P305+P351+P338-P362+P364-P303+P361+P353-P332+P313-P403+P235 |
UN# : | 1325 | Class : | 4.1 |
Hazard Statements : | H315-H319-H228 | Packing Group : | Ⅱ |