354-69-8 | 1,1,1,2,2-Pentafluoro-3-iodopropane

CAS:354-69-8 | 1,1,1,2,2-Pentafluoro-3-iodopropane ,Description

1,1,1,2,2-Pentafluoro-3-iodopropane is a fluorinated organic compound with a unique combination of physical and chemical properties. It is a colorless liquid with a boiling point of -7°C and a molecular weight of 310.07 g/mol. As a halogenated hydrocarbon, 1,1,1,2,2-pentafluoro-3-iodopropane has numerous applications in scientific research, including synthesis and analysis, as well as biochemical and physiological studies. 
 

Scientific Research Applications

Radical Additions to Unsaturated Systems

1,1,1,2,2-Pentafluoro-3-iodopropane has been investigated in the context of radical additions to unsaturated systems. Research by Gregory, Haszeldine, and Tipping (1968) demonstrated the photochemical reaction of chloro-1,1-difluoroethylene with trifluoroiodomethane, yielding adducts including 3-chloro-1,1,1,2,2-pentafluoro-3-iodopropane (Gregory, Haszeldine, & Tipping, 1968).

Reactions with Vinyl Fluoride and Trifluoroethylene

The compound also plays a role in reactions with vinyl fluoride and trifluoroethylene. Fleming, Haszeldine, and Tipping (1973) reported that heptafluoro-2-iodopropane reacts under photochemical conditions with these substances, forming various adducts that shed light on the mechanisms of these reactions (Fleming, Haszeldine, & Tipping, 1973).

Fluorocarbon-Aluminium Compound Reactions

Dickson and Sutcliffe (1972) studied the reactions of 1,1,1,2,2-Pentafluoro-3-iodopropane with lithium tetrahydroaluminate, leading to the formation of unstable complexes. These findings are significant in understanding the properties and reactivity of fluorocarbon-aluminium compounds (Dickson & Sutcliffe, 1972).

Synthesis of Perfluoro-(3-methylbuta-1,2-diene)

Banks et al. (1969) reported the synthesis of Perfluoro-(3-methylbuta-1,2-diene) through dehydrohalogenation processes involving 1,1,1,2,2-Pentafluoro-3-iodopropane. This study contributes to the field of polymer chemistry and the synthesis of fluorinated organic compounds (Banks, Braithwaite, Haszeldine, & Taylor, 1969).

Perfluoroalkyl Derivatives of Sulphur

Research by Banks et al. (1974) explored the reactions of perfluorovinylsulphur pentafluoride with various compounds, including 1,1,1,2,2-Pentafluoro-3-iodopropane. This work is crucial in understanding the chemical behavior of perfluoroalkyl derivatives of sulphur (Banks, Barlow, Haszeldine, & Morton, 1974).

Telomerization Reactions in Fluorocarbon Polymers

Chambers et al. (1964) investigated the use of heptafluoro-2-iodopropane in telomerization reactions, a process relevant for the synthesis of fluorocarbon polymers. The study provided insights into the efficiency of iodides as chain-transfer agents in these reactions (Chambers, Hutchinson, Mobbs, & Musgrave, 1964).

Photoelectron Spectroscopy Studies

The photoelectron spectra of various iodine-containing molecules, including 1,1,1,2,2-Pentafluoro-3-iodopropane, have been measured by Boschi and Salahub (1974). This research is vital for understanding the electronic structure and properties of these molecules (Boschi & Salahub, 1974).

Fourier Transform Microwave Spectroscopy

Grubbs, Bailey, and Cooke (2009) conducted studies using chirped pulse Fourier transform microwave spectroscopy on 1,1,1,2,2-Pentafluoro-3-iodopropane. This research is crucial for understanding the molecular structure and behavior of such compounds (Grubbs, Bailey, & Cooke, 2009).

Vibrational Spectra and Rotational Isomerism

Ogawa et al. (1978) explored the vibrational spectra and rotational isomerism of halogenoalkanes, which could include studies related to compounds like 1,1,1,2,2-Pentafluoro-3-iodopropane. Such studies provide valuable information about the physical properties of these molecules (Ogawa, Imazeki, Yamaguchi, Matsuura, Harada, & Shimanouchi, 1978).

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