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3832-48-2 | Bromodifluoroacetyl chloride

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Bromodifluoroacetyl chloride (BDFA) is a halogenated alkylating agent that is widely used in scientific research applications. It is a colorless, volatile liquid that is highly reactive and has a wide range of uses in both organic and inorganic chemistry. BDFA has been used in a variety of research applications, includ...

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CAS:3832-48-2 | Bromodifluoroacetyl chloride ,Description

Bromodifluoroacetyl chloride (BDFA) is a halogenated alkylating agent that is widely used in scientific research applications. It is a colorless, volatile liquid that is highly reactive and has a wide range of uses in both organic and inorganic chemistry. BDFA has been used in a variety of research applications, including the synthesis of organic compounds and the study of biochemical and physiological processes. 
 

Scientific Research Applications

 

Synthesis and Molecular Studies

  • Bromodifluoroacetyl fluoride (CF2BrC(O)F), closely related to bromodifluoroacetyl chloride, was prepared through a gas-phase reaction and studied using FTIR spectroscopy and low-temperature matrix isolation. This research contributes to understanding the molecular properties and potential applications of related compounds (Arce, Czarnowski, & Romano, 2006).

Photodissociation Studies

  • Bromopropionyl chloride, structurally similar to bromodifluoroacetyl chloride, was studied to understand the branching between C–Br and C–Cl bond fission following excitation. Such studies help in comprehending the molecular behavior under different conditions, which could be relevant for similar compounds like bromodifluoroacetyl chloride (Kash, Waschewsky, Butler, & Francl, 1993) .

Structural Analysis through Electron Diffraction

  • Gas phase electron diffraction studies on bromoacetyl chloride and bromide, compounds related to bromodifluoroacetyl chloride, provided insights into their molecular structure and conformation. This information is crucial for understanding the physical properties and potential applications of bromodifluoroacetyl chloride (Steinnes, Shen, & Hagen, 1980).

Catalytic Applications

  • Copper-catalyzed bromodifluoroacetylative cyclization of enynes was described, showcasing the compound's utility in catalysis and organic synthesis. Such reactions contribute to the development of novel chemical processes involving bromodifluoroacetyl chloride derivatives (Zhu et al., 2020).
  • In another study, copper-catalyzed bromodifluoroacetylation of alkenes was demonstrated using bromodifluoroacetate, a derivative of bromodifluoroacetyl chloride. This highlights its potential in facilitating novel organic transformations (Li, Mao, Huang, & Zhu, 2018).

Environmental Impact Studies

  • The effect of bromide ion on haloacetic acid speciation resulting from chlorination and chloramination was studied, which can include compounds like bromodifluoroacetyl chloride. Understanding these reactions is important for assessing the environmental impact and safety of such chemicals (Cowman & Singer, 1996).

More Information

 

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MS

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IR1

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IR2

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