423-39-2 | Perfluorobutyl iodide

CAS:423-39-2 | Perfluorobutyl iodide ,Description

Perfluorobutyl iodide (PFBI) is an organofluorine compound that is widely used in industrial and scientific research. It is a colorless liquid with a low boiling point and a high vapor pressure, making it an ideal solvent for various applications. PFBI is also known as perfluoro-2-butyl-iodide, perfluoro-2-iodobutane, perfluorobutyl iodide, and perfluorobutyl iodide-1-oxide. It is primarily used in the synthesis of organic and inorganic compounds, as well as in the production of pharmaceuticals, agrochemicals, and other specialty chemicals.
 

Scientific Research Applications

• Surface Chemistry Studies: It is used to study the chemistry of perfluorobutyl groups on diamond surfaces, providing insights into surface modifications and interactions (Kim, Mowrey, Butler & Russell, 1998).
• Solar-Pumped Lasers: Perfluorobutyl iodides have shown superior performance in solar-pumped lasers, demonstrating equal gain to n-C3F7I, making them valuable in laser technology (Lee, Weaver & Tabibi, 1988).
• Organic Synthesis: It is efficient and versatile in the synthesis of fluorine-containing organic compounds, highlighting its significance in pharmaceutical and material science applications (Brace, 1999).
• Halogen Bonding Studies: In complexes with hydrogen-bond acceptors, perfluorohexyl iodide helps probe non-covalent interactions like halogen bonding and hydrogen bonding (Cabot & Hunter, 2009).
• Iodine Lasers: It is applied extensively in iodine lasers, with its properties being crucial for understanding and optimizing laser performance (Zhao Shu, 2009).
• Raw Material in Synthesis: Used as a raw material in preparing specific compounds like 3-perfluorohexyl-1,2-epoxypropane (PFOP), it demonstrates its utility in organic chemical synthesis (Wang Ming-gang, 2012).
• Photochemical Perfluoroalkylation Reactions: A new protocol involving perfluoroalkyl iodide is used for synthesizing perfluoroalkyl-substituted compounds, underscoring its role in photochemistry (Wang et al., 2017).
• Cyanomethylation of Azoles and Phenols: Assists in the cyanomethylation of azoles and phenols with acetonitrile, contributing to organic synthesis and pharmaceutical research (Zhang, Wu, Ji & Cao, 2015).
• Photochemical Additions: Reacts photochemically with alkynes and unsaturated organic compounds, indicating its role in chemical transformations and synthesis (Habib & Mallouk, 1991).
• Synthesis of Silicon Network Polymers: Perfluorobutyl-substituted polysilynes, synthesized using perfluorobutyl iodide, display the characteristics of a silicon network polymer, showing its importance in polymer chemistry (Watanabe, Ito & Miwa, 1995).
• Intermediates in Synthesis of Fluorinated Compounds: It's used as an intermediate in synthesizing partially fluorinated compounds, such as acids and aldehydes, highlighting its role in diverse chemical syntheses (Furin, 2000).
• Addition to C-C Multiple Bonds: Can be efficiently added to carbon-carbon multiple bonds, emphasizing its utility in organic reactions (Guo, 1995).
• Alternative Surfactants Synthesis: Used in synthesizing perfluorobutyl substituted disodium alkanesulfonates, offering alternatives to well-known surfactants like perfluorooctanesulfonic acid (PFOS) (Bodduri et al., 2014).
• Preparation of Perfluoroallyl Reagents: Reacts to produce F-allylcadmium and F-allylcopper reagents, useful in organic synthesis (Burton, Tarumi & Heinze, 1990).
• Synthesis of Perfluoroalkyl Nitroso Compounds: Perfluoroalkyl nitroso compounds can be prepared by irradiation of perfluoroiodide, demonstrating its role in creating stable compounds (Banus, 1953).
• Electrochemical Studies: The electrochemical reduction of perfluoro-n-hexyl iodide yields organomercuric compounds, highlighting its importance in electrochemistry (Calas, Moreau & Commeyras, 1977).
• Environmental Impact Studies: Polyfluorinated iodides like PFIs, related to perfluorobutyl iodide, are found in the environment and can transform into various fluorinated compounds, underscoring the environmental impact and behavior of these substances (Ruan et al., 2010).
• Krespan Method in Synthesis: The synthesis of perfluoro-t-butyl iodide can be performed using the Krespan method, showing its application in synthetic chemistry (Ching, 1966).

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